Issue 31, 2009
From the journal:

Chemical Communications

Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO2-expanded liquids†

Daniel del Moral,a   Anna M. Banet Osuna,ab   Alba Córdoba,bc   Josep M. Moretó,a   Jaume Veciana,bc   Susagna Ricart*a  and  Nora Ventosa*bc  

* Corresponding authors

a Homogeneous Catalysis Group, Institut de Ciència de Materials de Barcelona (CSIC), UAB Campus, Spain
E-mail: ricart@icmab.es
Fax: +34 935 805 729
Tel: +34 935 801 853

b Molecular Nanoscience and Organic Materials Department, Institut de Ciència de Materials de Barcelona (CSIC), UAB Campus, Spain
E-mail: ventosa@icmab.es
Fax: +34 935 805 729
Tel: +34 935 801 853

c Networking Research Center on Bioengineering Biomaterials and Nanomedicine (CIBER-BBN), Spain

Abstract

Selective mono or double carbonylations could be achieved by using CO2-expanded liquids in [2 + 2 + 1] carbonylative reactions of alkenes or acetylenes with allyl bromides catalyzed by Ni(I).

Graphical abstract: Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO2-expanded liquids

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Article information

DOI
https://doi.org/10.1039/B908253K
Article type
Communication
Submitted
24 Apr 2009
Accepted
02 Jun 2009
First published
29 Jun 2009

Chem. Commun., 2009, 4723-4725

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Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO2-expanded liquids

D. del Moral, A. M. Banet Osuna, A. Córdoba, J. M. Moretó, J. Veciana, S. Ricart and N. Ventosa, Chem. Commun., 2009, 4723 DOI: 10.1039/B908253K

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