Issue 35, 2009
From the journal:

Dalton Transactions

Direct observation of a carbonylation reaction relevant to CO/alkenecopolymerization in a methylpalladium carbonyl complex containing a bis(N-heterocyclic carbene) ligand†

Sri S. Subramaniuma  and  LeGrande M. Slaughter*a  

* Corresponding authors

a Department of Chemistry, Oklahoma State University, Stillwater, OK, USA
E-mail: lms@chem.okstate.edu
Fax: 405-744-6007
Tel: 405-744-5941

Abstract

Use of a bulky bidentate bis(NHC) ligand allows isolation of a stable cationic methylpalladium carbonyl complex that undergoes clean carbonylation to an acyl complex under excess CO, modeling a key step in CO/alkene copolymerization.

Graphical abstract: Direct observation of a carbonylation reaction relevant to CO/alkene copolymerization in a methylpalladium carbonyl complex containing a bis(N-heterocyclic carbene) ligand

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Article information

DOI
https://doi.org/10.1039/B908689G
Article type
Communication
Submitted
01 May 2009
Accepted
02 Jul 2009
First published
10 Jul 2009

Dalton Trans., 2009, 6930-6933

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Direct observation of a carbonylation reaction relevant to CO/alkene copolymerization in a methylpalladium carbonyl complex containing a bis(N-heterocyclic carbene) ligand

S. S. Subramanium and L. M. Slaughter, Dalton Trans., 2009, 6930 DOI: 10.1039/B908689G

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