Issue 4, 2010
From the journal:

CrystEngComm

A 3D porous metal–organic framework constructed of 1D zigzag and helical chains exhibiting selective anion exchange†

Dengxu Wang,‡a   Haiyan He,‡a   Xiaohui Chen,a   Shengyu Feng,*a   Yuzhong Niua  and  Daofeng Sun*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Shandong University, Jinan, P. R. China
E-mail: fsy@sdu.edu.cn, dfsun@sdu.edu.cn.
Fax: (+86)531 8856 4464
Tel: (+86) 531 8836 4866

Abstract

Slow diffusion of AgClO44 with Me2Si [(4-(Im-1-yl)Ph]2 (BIPS) yields the crystalline complex 1 with a 3D-braided porous metal–organic framework via self-assembly of two series of 1D polymer chains through both braiding and interpenetrating. Complex 1 consists of two distinct kinds of channels with different sizes and shapes along a and b directions occupied by perchlorate anions and water molecules.

Graphical abstract: A 3D porous metal–organic framework constructed of 1D zigzag and helical chains exhibiting selective anion exchange

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Article information

DOI
https://doi.org/10.1039/B910988A
Article type
Communication
Submitted
04 Jun 2009
Accepted
31 Oct 2009
First published
09 Nov 2009

CrystEngComm, 2010,12, 1041-1043

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A 3D porous metal–organic framework constructed of 1D zigzag and helical chains exhibiting selective anion exchange

D. Wang, H. He, X. Chen, S. Feng, Y. Niu and D. Sun, CrystEngComm, 2010, 12, 1041 DOI: 10.1039/B910988A

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