Issue 41, 2009
From the journal:

Chemical Communications

Homogeneous catalytic transfer dehydrogenation of alkanes with a group 10 metal center†

Eugene Khaskin,a   Daniel L. Lew,a   Shrinwantu Pala  and  Andrei N. Vedernikov*a  

* Corresponding authors

a University of Maryland Chemistry & Biochemistry, College Park, USA
E-mail: avederni@umd.edu
Tel: +1-301-405-2784

Abstract

Unambiguous catalytic homogeneous alkane transfer dehydrogenation was observed with a group 10 metal complex catalyst, LPtII(cyclo-C6H10)H, supported by a lipophilic dimethyl-di(4-tert-butyl-2-pyridyl)borate anionic ligand and tert-butylethene as the sacrificial hydrogen acceptor.

Graphical abstract: Homogeneous catalytic transfer dehydrogenation of alkanes with a group 10 metal center

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Article information

DOI
https://doi.org/10.1039/B913319D
Article type
Communication
Submitted
06 Jul 2009
Accepted
20 Aug 2009
First published
03 Sep 2009

Chem. Commun., 2009, 6270-6272

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Homogeneous catalytic transfer dehydrogenation of alkanes with a group 10 metal center

E. Khaskin, D. L. Lew, S. Pal and A. N. Vedernikov, Chem. Commun., 2009, 6270 DOI: 10.1039/B913319D

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