Issue 10, 2009
From the journal:

Green Chemistry

Asymmetric Baeyer–Villiger oxidation with Co(Salen) and H2O2 in water: striking supramolecular micelles effect on catalysis

Giulio Bianchini,a   Alessandra Cavarzan,a   Alessandro Scarso*a  and  Giorgio Strukul*a  

* Corresponding authors

a Dipartimento di Chimica, Università Ca’ Foscari di Venezia, Dorsoduro 2137, Venezia, Italy
E-mail: alesca@unive.it, strukul@unive.it
Fax: +39-041-2348517
Tel: +39-041-2348569

Abstract

A micellar environment enables catalytic, diastereoselective and enantioselective Baeyer–Villiger oxidation of cyclobutanones (ee up to 90%) with H2O2 as oxidant using Co(Salen) catalyst 1, while the same catalytic system is inactive in organic solvents.

Graphical abstract: Asymmetric Baeyer–Villiger oxidation with Co(Salen) and H2O2 in water: striking supramolecular micelles effect on catalysis

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Article information

DOI
https://doi.org/10.1039/B916262N
Article type
Communication
Submitted
18 May 2009
Accepted
06 Aug 2009
First published
14 Aug 2009

Green Chem., 2009,11, 1517-1520

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Asymmetric Baeyer–Villiger oxidation with Co(Salen) and H2O2 in water: striking supramolecular micelles effect on catalysis

G. Bianchini, A. Cavarzan, A. Scarso and G. Strukul, Green Chem., 2009, 11, 1517 DOI: 10.1039/B916262N

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