Issue 11, 2010

Successive catalytic reactions specific to Pd-based rotaxane complexes as a result of wheel translation along the axle

Abstract

Rotaxane-structure-specific Pd-catalyzed rearrangement of propargyl or allyl urethanegroups to oxazolidinone moieties proceeded efficiently. The conversion took place successively by the translation of the wheel along the axle, thus providing a novel macrocyclic catalytic system.

Graphical abstract: Successive catalytic reactions specific to Pd-based rotaxane complexes as a result of wheel translation along the axle

Supplementary files

Article information

Article type
Communication
Submitted
18 Aug 2009
Accepted
22 Dec 2009
First published
18 Jan 2010

Chem. Commun., 2010,46, 1920-1922

Successive catalytic reactions specific to Pd-based rotaxane complexes as a result of wheel translation along the axle

N. Miyagawa, M. Watanabe, T. Matsuyama, Y. Koyama, T. Moriuchi, T. Hirao, Y. Furusho and T. Takata, Chem. Commun., 2010, 46, 1920 DOI: 10.1039/B917053G

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