Issue 1, 2010
From the journal:

Dalton Transactions

Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations†

William Clegg,a   Ben Conway,*b   Pablo García-Álvarez,b   Alan R. Kennedy,b   Jan Klett,b   Robert E. Mulvey*b  and  Luca Russoa  

* Corresponding authors

a School of Chemistry, Newcastle University, Newcastle-upon-Tyne, UK

b WestCHEM Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK
E-mail: r.e.mulvey@strath.ac.uk

Abstract

Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA·K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA·K(μ-Me)2Zn(Fc)}∞] and [{PMDETA·K(μ-Me)2Zn(Rc)}2], respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.

Graphical abstract: Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations

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Article information

DOI
https://doi.org/10.1039/B917202P
Article type
Communication
Submitted
13 May 2009
Accepted
16 Sep 2009
First published
30 Sep 2009

Dalton Trans., 2010,39, 62-65

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Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations

W. Clegg, B. Conway, P. García-Álvarez, A. R. Kennedy, J. Klett, R. E. Mulvey and L. Russo, Dalton Trans., 2010, 39, 62 DOI: 10.1039/B917202P

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