Issue 1, 2010

pH-Controlled change of the coordination modes of the highly symmetrical multitopic ligand and metal–oxygen arrays for constructing coordination assemblies

Abstract

For the first time, the effect of the pH value on the coordination assemblies of a highly symmetrical multitopic ligand has been systematically investigated, indicating that higher pH values lead to increase of the coordination ability of the ligand, the amount of hydroxide incorporated into the structures, and the degree of condensation of metal polyhedra in the resulting 3D networks.

Graphical abstract: pH-Controlled change of the coordination modes of the highly symmetrical multitopic ligand and metal–oxygen arrays for constructing coordination assemblies

Supplementary files

Article information

Article type
Communication
Submitted
20 Aug 2009
Accepted
24 Aug 2009
First published
04 Sep 2009

CrystEngComm, 2010,12, 49-51

pH-Controlled change of the coordination modes of the highly symmetrical multitopic ligand and metal–oxygen arrays for constructing coordination assemblies

B. Zheng, J. Bai and Z. Zhang, CrystEngComm, 2010, 12, 49 DOI: 10.1039/B917258K

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