Issue 12, 2009
From the journal:

Green Chemistry

Creation of highly stable monomeric Pd(II) species in an anion-exchangeable hydroxy double salt interlayer: Application to aerobic alcohol oxidation under an air atmosphere†

Takayoshi Hara,a   Masakazu Ishikawa,a   Junya Sawada,a   Nobuyuki Ichikunia  and  Shogo Shimazu*a  

* Corresponding authors

a Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33, Yayoi-cho, Inage-ku, Chiba
E-mail: shimazu@faculty.chiba-u.jp
Fax: +81-43-290-3379

Abstract

An active Pd(II) catalyst supported on the Ni–Zn mixed basic salt (NiZn), which is classified by the anion-exchangeable layered hydroxy double salts, was synthesized by simple intercalation of the anionic Pd(II) hydroxyl complex. The divalent Pd species in the interlayer of NiZn maintained their original monomeric structure during the aerobic alcohol oxidation, due to the strong electrostatic interaction between the NiZn host and anionic Pd(II) species. This catalyst could be reused without any loss of the catalytic activity and selectivity in the aerobic alcohol oxidation.

Graphical abstract: Creation of highly stable monomeric Pd(II) species in an anion-exchangeable hydroxy double salt interlayer: Application to aerobic alcohol oxidation under an air atmosphere

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Article information

DOI
https://doi.org/10.1039/B918350G
Article type
Paper
Submitted
26 Jun 2009
Accepted
04 Sep 2009
First published
23 Oct 2009

Green Chem., 2009,11, 2034-2040

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Creation of highly stable monomeric Pd(II) species in an anion-exchangeable hydroxy double salt interlayer: Application to aerobic alcohol oxidation under an air atmosphere

T. Hara, M. Ishikawa, J. Sawada, N. Ichikuni and S. Shimazu, Green Chem., 2009, 11, 2034 DOI: 10.1039/B918350G

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