Issue 5, 2010
From the journal:

Chemical Communications

BN benzonitrile: an electron-deficient 1,2-dihydro-1,2-azaborine featuring linkage isomerism†

Adam J. V. Marwitz,a   Sean P. McClintock,‡a   Lev N. Zakharov‡a  and  Shih-Yuan Liu*a  

* Corresponding authors

a Department of Chemistry, University of Oregon, Eugene, Oregon 97403, USA
E-mail: lsy@uoregon.edu, lev@uoregon.edu, smcclint@uoregon.edu
Fax: +1 (541) 346-0487
Tel: +1 (541) 346-5573

Abstract

BN Benzonitrile 2, a 1,2-dihydro-1,2-azaborine bearing an electron-withdrawing boron substituent was prepared and characterized, and its coordination chemistry investigated; reactivity studies revealed that BN benzonitrile 2 undergoes BCN–BNC linkage isomerism upon coordination to Cr(CO)5.

Graphical abstract: BN benzonitrile: an electron-deficient 1,2-dihydro-1,2-azaborine featuring linkage isomerism

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Article information

DOI
https://doi.org/10.1039/B919632C
Article type
Communication
Submitted
23 Sep 2009
Accepted
11 Nov 2009
First published
25 Nov 2009

Chem. Commun., 2010,46, 779-781

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BN benzonitrile: an electron-deficient 1,2-dihydro-1,2-azaborine featuring linkage isomerism

A. J. V. Marwitz, S. P. McClintock, L. N. Zakharov and S. Liu, Chem. Commun., 2010, 46, 779 DOI: 10.1039/B919632C

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