Issue 3, 2010
From the journal:

Chemical Communications

Condensation of nitriles with amides promoted by coordinatively unsaturated bis-nickel(ii)-hydroxy complex: a new route to alkyl- and aryl-imidoylamidines†

Jeffrey P. Wikstrom,a   Alexander S. Filatovb  and  Elena V. Rybak-Akimova*a  

* Corresponding authors

a Tufts University, 62 Talbot Ave, Medford, MA, USA
E-mail: Elena.rybak-akimova@tufts.edu
Fax: +1-617-627-3443
Tel: 617-627-3413

b SUNY Albany, 1400 Washington Aves, Albany, NY, USA
E-mail: afilatov@albany.edu

Abstract

A pentacoordinate bis(μ-hydroxy) nickel dimer promotes formation of alkyl- and aryl-imidoylamidines from nitriles and ureas or amides under mild conditions.

Graphical abstract: Condensation of nitriles with amides promoted by coordinatively unsaturated bis-nickel(ii)-hydroxy complex: a new route to alkyl- and aryl-imidoylamidines

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Article information

DOI
https://doi.org/10.1039/B919634J
Article type
Communication
Submitted
21 Sep 2009
Accepted
16 Nov 2009
First published
03 Dec 2009

Chem. Commun., 2010,46, 424-426

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Condensation of nitriles with amides promoted by coordinatively unsaturated bis-nickel(II)-hydroxy complex: a new route to alkyl- and aryl-imidoylamidines

J. P. Wikstrom, A. S. Filatov and E. V. Rybak-Akimova, Chem. Commun., 2010, 46, 424 DOI: 10.1039/B919634J

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