Issue 7, 2010

Unusual reactivities of N-heterocyclic carbenes upon coordination to the platinum(ii)–dimethyl moiety

Abstract

Unsaturated NHCs of varying steric bulk undergo a series of unusual oxidative addition and reductive elimination processes upon binding to the Pt(Me)2 fragment.

Graphical abstract: Unusual reactivities of N-heterocyclic carbenes upon coordination to the platinum(ii)–dimethyl moiety

Supplementary files

Article information

Article type
Communication
Submitted
01 Oct 2009
Accepted
22 Dec 2009
First published
13 Jan 2010

Chem. Commun., 2010,46, 1050-1052

Unusual reactivities of N-heterocyclic carbenes upon coordination to the platinum(II)–dimethyl moiety

G. C. Fortman, N. M. Scott, A. Linden, E. D. Stevens, R. Dorta and S. P. Nolan, Chem. Commun., 2010, 46, 1050 DOI: 10.1039/B920482B

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