Issue 15, 2010
From the journal:

Chemical Communications

Chirality and magnetism of an open-framework cobalt phosphite containing helical channels from achiral materials†

Xianchun Liu,a   Yan Xing,*a   Xinlong Wang,a   Hongbin Xu,b   Xizheng Liu,a   Kuizhan Shaoa  and  Zhongmin Su*a  

* Corresponding authors

a Department of Chemistry, Northeast Normal University, Changchun, P. R. China
E-mail: xingyan69cn@yahoo.com.cn, zmsu@nenu.edu.cn
Fax: +86-431-8509-9108
Tel: +86-431-8610-5529

b China Science and Technology Exchange Center, Ministry of Science and Technology, Beijing, P. R. China

Abstract

A new chiral open-framework cobalt phosphite [C6N2H14][Co(HPO3)2] (1) with helical channels has been synthesized under solvothermal conditions in the presence of achiral organic amine. The circular dichroism (CD) spectrum indicates that the bulk crystals have optical activity. Magnetic measurements reveal that 1 is a weak ferromagnet.

Graphical abstract: Chirality and magnetism of an open-framework cobalt phosphite containing helical channels from achiral materials

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Article information

DOI
https://doi.org/10.1039/B923028A
Article type
Communication
Submitted
03 Nov 2009
Accepted
05 Feb 2010
First published
24 Feb 2010

Chem. Commun., 2010,46, 2614-2616

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Chirality and magnetism of an open-framework cobalt phosphite containing helical channels from achiral materials

X. Liu, Y. Xing, X. Wang, H. Xu, X. Liu, K. Shao and Z. Su, Chem. Commun., 2010, 46, 2614 DOI: 10.1039/B923028A

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