Issue 5, 2010
From the journal:

Chemical Communications

Tailoring dicobalt Pacman complexes of Schiff-base calixpyrroles towards dioxygenreduction catalysis†

Elham Askarizadeh,ab   Sahar Bani Yaghoob,ab   Davar M. Boghaei,b   Alexandra M. Z. Slawinc  and  Jason B. Love*a  

* Corresponding authors

a EaStCHEM School of Chemistry, University of Edinburgh, Joseph Black Building, The King’s Buildings, West Mains Road, Edinburgh, UK
E-mail: jason.love@ed.ac.uk
Fax: +44 (0)131 6504743

b Department of Chemistry, Sharif University of Technology, P.O. Box 11155-3516, Tehran, Iran

c EaStCHEM School of Chemistry, University of St. Andrews, North Haugh, St. Andrews, Fife, UK

Abstract

By modifying the mouth of a macrocyclic dicobalt Pacman complex, it is possible to both isolate new bridging-superoxo and hydroxyl complexes and to tune the reactivity of this system towards catalytic four-electron reduction of dioxygen to water.

Graphical abstract: Tailoring dicobalt Pacman complexes of Schiff-base calixpyrroles towards dioxygen reduction catalysis

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Article information

DOI
https://doi.org/10.1039/B923189G
Article type
Communication
Submitted
05 Nov 2009
Accepted
03 Dec 2009
First published
18 Dec 2009

Chem. Commun., 2010,46, 710-712

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Tailoring dicobalt Pacman complexes of Schiff-base calixpyrroles towards dioxygen reduction catalysis

E. Askarizadeh, S. B. Yaghoob, D. M. Boghaei, A. M. Z. Slawin and J. B. Love, Chem. Commun., 2010, 46, 710 DOI: 10.1039/B923189G

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