Issue 25, 2010
From the journal:

Chemical Communications

Anion-templated syntheses of octanuclear silverclusters from a silver dithiophosphate chain†

C. W. Liu,*a   How-Wei Chang,a   Ching-Shiang Fang,a   Bijay Sarkara  and  Ju-Chun Wangb  

* Corresponding authors

a Department of Chemistry, National Dong Hwa University, Hualien, Taiwan, ROC
E-mail: chenwei@mail.ndhu.edu.tw
Fax: +886-3-863 3570
Tel: +886-3-863 3607

b Department of Chemistry, Soochow University, Taipei, Taiwan, ROC

Abstract

Extended chain polymers [Ag5{S2P(OEt)2}4(PF6)]n, (1) could be converted to clusters of the type, [Ag8(X){S2P(OEt)2}6](PF6) [X = F (2); Cl (3); H (4)], by the addition of appropriate anions, of which [Ag8(H){S2P(OEt)2}6]+ showed a unique tetracapped-tetrahedral Ag8 core and contained Ag-μ-H–Ag linkages.

Graphical abstract: Anion-templated syntheses of octanuclear silver clusters from a silver dithiophosphate chain

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Article information

DOI
https://doi.org/10.1039/B923388A
Article type
Communication
Submitted
09 Nov 2009
Accepted
13 May 2010
First published
27 May 2010

Chem. Commun., 2010,46, 4571-4573

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Anion-templated syntheses of octanuclear silver clusters from a silver dithiophosphate chain

C. W. Liu, H. Chang, C. Fang, B. Sarkar and J. Wang, Chem. Commun., 2010, 46, 4571 DOI: 10.1039/B923388A

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