Issue 6, 2010
From the journal:

Chemical Communications

Platinum substituted boroles†

Holger Braunschweig,*a   Ching-Wen Chiu,a   Krzysztof Radackia  and  Peter Brennera  

* Corresponding authors

a Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany
E-mail: h.braunschweig@mail.uni-wuerzburg.de
Fax: +49 931 888 4623
Tel: +49 931 888 5261

Abstract

The unprecedented 1-metalloborole [(Cy3P)2Pt(Cl)(BC4Ph4)] (1) and its T-shaped cationic derivative (2) were successfully prepared and structurally characterized. Fine-tuning the electronics of the boron-bound metal complex leads to a significant change in the lowest electronic transition energy of the 1-metalloboroles.

Graphical abstract: Platinum substituted boroles

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Article information

DOI
https://doi.org/10.1039/B923652J
Article type
Communication
Submitted
12 Nov 2009
Accepted
15 Dec 2009
First published
11 Jan 2010

Chem. Commun., 2010,46, 916-918

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Platinum substituted boroles

H. Braunschweig, C. Chiu, K. Radacki and P. Brenner, Chem. Commun., 2010, 46, 916 DOI: 10.1039/B923652J

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