Issue 17, 2010

Single-ion magnets based on mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)3L] (Ln = Sm, Eu, Gd, Tb and Dy)

Abstract

A series of mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)3L] [Ln = Dy(1), Sm(2), Eu(3), Gd(4), and Tb(5), L = (S,S)-2,2′-Bis(4-benzyl-2-oxazoline)] were synthesized and characterized. Among these complexes, complex 1 represents the first example of mononuclear lanthanide complexes displaying single-ion magnet behavior and ferroelectricity.

Graphical abstract: Single-ion magnets based on mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)3L] (Ln = Sm, Eu, Gd, Tb and Dy)

Supplementary files

Article information

Article type
Communication
Submitted
24 Nov 2009
Accepted
02 Mar 2010
First published
24 Mar 2010

Chem. Commun., 2010,46, 2929-2931

Single-ion magnets based on mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)3L] (Ln = Sm, Eu, Gd, Tb and Dy)

D. Li, T. Wang, C. Li, D. Liu, Y. Li and X. You, Chem. Commun., 2010, 46, 2929 DOI: 10.1039/B924547B

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