Issue 20, 2010

Pressure effect on the three-dimensional charge-transfer ferromagnet [{Ru2(m-FPhCO2)4}2(BTDA-TCNQ)]

Abstract

The magnetic properties of a three-dimensional infinite network compound, [{Ru2(m-FPhCO2)4}2(BTDA-TCNQ)] (m-FPhCO2 = m-fluorobenzoate; BTDA-TCNQ = bis(1,2,5-thiadiazolo)tetracyanoquinodimethane), were investigated under hydrostatic pressures up to 12.9 kbar. The applied pressure caused the intralattice exchange couplings to weaken, inducing a decrease in the magnetic phase transition temperature from 107 K at ambient pressure to 57 K at 12.9 kbar.

Graphical abstract: Pressure effect on the three-dimensional charge-transfer ferromagnet [{Ru2(m-FPhCO2)4}2(BTDA-TCNQ)]

Article information

Article type
Communication
Submitted
07 Dec 2009
Accepted
22 Jan 2010
First published
04 Feb 2010

Dalton Trans., 2010,39, 4724-4726

Pressure effect on the three-dimensional charge-transfer ferromagnet [{Ru2(m-FPhCO2)4}2(BTDA-TCNQ)]

N. Motokawa, H. Miyasaka and M. Yamashita, Dalton Trans., 2010, 39, 4724 DOI: 10.1039/B925685G

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