Issue 15, 2010

Abrupt spin transition around room temperature and light induced properties in FeII complexes with N4O2 coordination sphere

Abstract

Mononuclear spin-crossover complex FeII(L)2·CH3OH (1·CH3OH) and its desolvated product 1 exhibit abrupt spin transitions around room temperature. 1 also shows a light induced excited spin state trapping (LIESST) effect and a light induced thermal hysteresis (LITH) phenomenon at low temperature.

Graphical abstract: Abrupt spin transition around room temperature and light induced properties in FeII complexes with N4O2 coordination sphere

Supplementary files

Article information

Article type
Communication
Submitted
10 Dec 2009
Accepted
22 Feb 2010
First published
12 Mar 2010

Chem. Commun., 2010,46, 2554-2556

Abrupt spin transition around room temperature and light induced properties in FeII complexes with N4O2 coordination sphere

L. Zhang, G. Xu, H. Xu, T. Zhang, Z. Wang, M. Yuan and S. Gao, Chem. Commun., 2010, 46, 2554 DOI: 10.1039/B925917A

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