Issue 16, 2010
From the journal:

Chemical Communications

Enantioselective construction of allylic phosphine oxides through substitution of Morita–Baylis–Hillman carbonates with phosphine oxides†‡

Liang Hong,a   Wangsheng Sun,a   Chunxia Liu,a   Depeng Zhaoa  and  Rui Wang*ab  

* Corresponding authors

a State Key Laboratory of Applied Organic Chemistry and Institute of Biochemistry and Molecular Biology, Lanzhou University, Lanzhou, China
E-mail: wangrui@lzu.edu.cn
Fax: (+86) 931-891-2567

b Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Kowloon, Hong Kong

Abstract

The asymmetric organocatalytic allylic substitution reaction of MBH carbonates with phosphine oxides has been developed. This organocatalytic approach constitutes an easy and efficient method for the direct preparation of allylic phosphine oxides in high enantioselectivities.

Graphical abstract: Enantioselective construction of allylic phosphine oxides through substitution of Morita–Baylis–Hillman carbonates with phosphine oxides

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Article information

DOI
https://doi.org/10.1039/B926037D
Article type
Communication
Submitted
11 Dec 2009
Accepted
11 Feb 2010
First published
04 Mar 2010

Chem. Commun., 2010,46, 2856-2858

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Enantioselective construction of allylic phosphine oxides through substitution of Morita–Baylis–Hillman carbonates with phosphine oxides

L. Hong, W. Sun, C. Liu, D. Zhao and R. Wang, Chem. Commun., 2010, 46, 2856 DOI: 10.1039/B926037D

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