Issue 8, 2010

Rhodium-P,O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions

Abstract

We present new ureaphosphine ligands that coordinate in a P,O-bidentate fashion to rhodium(I). The ureaphosphine-Rh(I)-complexes were effectively used in the asymmetric hydrogenation of cyclic enamides giving high conversions and enantioselectivity.

Graphical abstract: Rhodium-P,O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions

Supplementary files

Article information

Article type
Communication
Submitted
09 Dec 2009
Accepted
17 Dec 2009
First published
06 Jan 2010

Dalton Trans., 2010,39, 1929-1931

Rhodium-P,O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions

J. Meeuwissen, R. J. Detz, A. J. Sandee, B. de Bruin and J. N. H. Reek, Dalton Trans., 2010, 39, 1929 DOI: 10.1039/B926043A

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