Issue 16, 2010
From the journal:

Chemical Communications

The intramolecular amination of allenes†

George C. Feast,a   Lee W. Pageb  and  Jeremy Robertson*a  

* Corresponding authors

a Department of Chemistry, Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, UK
E-mail: jeremy.robertson@chem.ox.ac.uk
Fax: +44 (0)1865 285002
Tel: +44 (0)1865 275660

b GlaxoSmithKline, New Frontiers Science Park, Third Avenue, Harlow, Essex, UK

Abstract

Rhodium-bound nitrenoids are trapped by tethered allenes generating acyloxy-enamines, aminocyclopropanes, and methylene aziridines. The aminocyclopropanes undergo substitution of the acetoxy group by a variety of nucleophiles.

Graphical abstract: The intramolecular amination of allenes

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Article information

DOI
https://doi.org/10.1039/B926179F
Article type
Communication
Submitted
11 Dec 2009
Accepted
01 Feb 2010
First published
26 Feb 2010

Chem. Commun., 2010,46, 2835-2837

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The intramolecular amination of allenes

G. C. Feast, L. W. Page and J. Robertson, Chem. Commun., 2010, 46, 2835 DOI: 10.1039/B926179F

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