Three's company: co-crystallization of a self-assembled S4 metallacyclophane with two diastereomeric metallacycle intermediates

Nathan R. Lindquist; Timothy G. Carter; Virginia M. Cangelosi; Lev N. Zakharov; Darren W. Johnson

doi:10.1039/B927034E

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Three's company: co-crystallization of a self-assembled S₄metallacyclophane with two diastereomeric metallacycle intermediates†

Nathan R. Lindquist,^a Timothy G. Carter,^a Virginia M. Cangelosi,^a Lev N. Zakharov^a and Darren W. Johnson*^a

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* Corresponding authors

^a Department of Chemistry and Material Science Institute, University of Oregon, and the Oregon Nanoscience and Microtechnologies Institute (ONAMI), Eugene, USA
E-mail: dwj@uoregon.edu
Fax: +1-541-346-0487
Tel: +1-541-346-1695

Abstract

Three discrete supramolecular self-assembled arsenic(III) complexes including an unusual S₄-symmetric tetranuclear [As₄L₂Cl₄] metallacyclophane and two diastereomeric cis/trans-[As₂LCl₂] metallacycle intermediates co-crystallize within a single crystal lattice.

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Article information

DOI: https://doi.org/10.1039/B927034E
Article type: Communication
Submitted: 06 Jan 2010
Accepted: 22 Feb 2010
First published: 09 Mar 2010

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Chem. Commun., 2010,46, 3505-3507

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Three's company: co-crystallization of a self-assembled S₄ metallacyclophane with two diastereomeric metallacycle intermediates

N. R. Lindquist, T. G. Carter, V. M. Cangelosi, L. N. Zakharov and D. W. Johnson, Chem. Commun., 2010, 46, 3505 DOI: 10.1039/B927034E

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