Issue 19, 2010
From the journal:

Dalton Transactions

Self-assembly of polyoxoselenitopalladate nanostars [Pd15(μ3-SeO3)10(μ3-O)10Na]9− and their supramolecular pairing in the solid state†

Massimiliano Delferro,*a   Claudia Graiff,b   Lisa Elvirib  and  Giovanni Predieri*b  

* Corresponding authors

a Department of Chemistry, Northwestern University, Evanston, Illinois, USA
E-mail: m-delferro@northwestern.edu

b Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica Università degli Studi di Parma, Viale G.P. Usberti 17/A, Parma, Italy
E-mail: giovanni.predieri@unipr.it
Fax: (+39) 0521 90 55 57
Tel: (+39) 0521 90 54 30

Abstract

An anionic Pd15-oxo-cluster [Pd15(μ3-SeO3)10(μ3-O)10Na]9− has been synthesized. It is the result of an unprecedented self-assembly of Pd2+ and Na+ cations, SeO32− and oxo anions. It has been found for the first time, that selenito groups can give rise to supramolecular interactions in the solid state with palladium atoms, through the selenium electron lone pairs.

Graphical abstract: Self-assembly of polyoxoselenitopalladate nanostars [Pd15(μ3-SeO3)10(μ3-O)10Na]9− and their supramolecular pairing in the solid state

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Article information

DOI
https://doi.org/10.1039/B927537A
Article type
Communication
Submitted
12 Jan 2010
Accepted
29 Mar 2010
First published
17 Apr 2010

Dalton Trans., 2010,39, 4479-4481

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Self-assembly of polyoxoselenitopalladate nanostars [Pd15(μ3-SeO3)10(μ3-O)10Na]9− and their supramolecular pairing in the solid state

M. Delferro, C. Graiff, L. Elviri and G. Predieri, Dalton Trans., 2010, 39, 4479 DOI: 10.1039/B927537A

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