Issue 22, 2010

Reversible modulation of π-association between 3,6-disubstituted carbazole ligands in a multistep assembling process

Abstract

Carbazole ligand (Im2Cz) forms a dimer complex ([(Im2Cz)4–Zn2+]2) that has multiple π-stacking interactions, after which the complex changes to a simple (Im2Cz)3Zn2+ complex that has no π-stacking carbazole ring via increased Zn2+ concentration.

Graphical abstract: Reversible modulation of π-association between 3,6-disubstituted carbazole ligands in a multistep assembling process

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
19 Jan 2010
Accepted
01 Apr 2010
First published
27 Apr 2010

Chem. Commun., 2010,46, 3929-3931

Reversible modulation of π-association between 3,6-disubstituted carbazole ligands in a multistep assembling process

N. Inukai, J. Yuasa and T. Kawai, Chem. Commun., 2010, 46, 3929 DOI: 10.1039/C001287D

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