Issue 26, 2010
From the journal:

Chemical Communications

Glycosylation with glycosyl N-phenyltrifluoroacetimidates (PTFAI) and a perspective of the future development of new glycosylation methods

Biao Yu*a  and  Jiansong Suna  

* Corresponding authors

a State Key Laboratory of Bio-organic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
E-mail: byu@mail.sioc.ac.cn
Fax: 86 21 64166128

Abstract

The glycosyl N-phenyltrifluoroacetimidates (PTFAI) have within the last ten years been applied in the synthesis of a wide variety of the oligosaccharides and glycoconjugates. Especially, these donors are found advantageous in glycosidic coupling with ‘arming’ sugar donors, ketose donors, and with less nucleophilic acceptors. A comprehensive review of the PTFAI donors is provided in a hope to reflect from a particular angle the current status and future trend of the glycosylation chemistry.

Graphical abstract: Glycosylation with glycosyl N-phenyltrifluoroacetimidates (PTFAI) and a perspective of the future development of new glycosylation methods

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Article information

DOI
https://doi.org/10.1039/C0CC00563K
Article type
Feature Article
Submitted
24 Mar 2010
Accepted
13 Apr 2010
First published
26 May 2010

Chem. Commun., 2010,46, 4668-4679

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Glycosylation with glycosyl N-phenyltrifluoroacetimidates (PTFAI) and a perspective of the future development of new glycosylation methods

B. Yu and J. Sun, Chem. Commun., 2010, 46, 4668 DOI: 10.1039/C0CC00563K

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