Synthesis of dimethylformamide from CO2, H2 and dimethylamine over Cu/ZnO

Jinli Liu; Chengkun Guo; Zhaofu Zhang; Tao Jiang; Huizhen Liu; Jinliang Song; Honglei Fan; Buxing Han

doi:10.1039/C0CC00751J

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Synthesis of dimethylformamide from CO₂, H₂ and dimethylamine over Cu/ZnO†

Jinli Liu,^a Chengkun Guo,^a Zhaofu Zhang,^a Tao Jiang,^a Huizhen Liu,^a Jinliang Song,^a Honglei Fan^a and Buxing Han*^a

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* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, P.R. China
E-mail: hanbx@iccas.ac.cn
Fax: (+86)10-62562821
Tel: (+86)10-62562821

Abstract

Cheap and simple Cu/ZnO catalysts are very effective and recyclable for the synthesis of dimethylformamide (DMF) from CO₂, H₂, and dimethylamine, and a yield of 97% can be reached.

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Supplementary files

Chemicals and catalyst characterization; the SEM, TEM, and HRTEM images of other catalysts PDF (549K)

Article information

DOI: https://doi.org/10.1039/C0CC00751J
Article type: Communication
Submitted: 03 Apr 2010
Accepted: 22 Jun 2010
First published: 09 Jul 2010

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Chem. Commun., 2010,46, 5770-5772

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Synthesis of dimethylformamide from CO₂, H₂ and dimethylamine over Cu/ZnO

J. Liu, C. Guo, Z. Zhang, T. Jiang, H. Liu, J. Song, H. Fan and B. Han, Chem. Commun., 2010, 46, 5770 DOI: 10.1039/C0CC00751J

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