Issue 29, 2010

Unprecedented thermal rearrangement of push–pull-chromophore–[60]fullerene conjugates: formation of chiral 1,2,9,12-tetrakis-adducts

Abstract

Push–pull-chromophore[60]fullerene conjugates featuring N,N-dimethylanilino-substituted 1,1,4,4-buta-1,3-dienes directly attached to the carbon sphere are transformed into chiral 1,2,9,12-tetrakis-adducts by a novel thermal rearrangement pathway.

Graphical abstract: Unprecedented thermal rearrangement of push–pull-chromophore–[60]fullerene conjugates: formation of chiral 1,2,9,12-tetrakis-adducts

Supplementary files

Article information

Article type
Communication
Submitted
12 Apr 2010
Accepted
24 May 2010
First published
17 Jun 2010

Chem. Commun., 2010,46, 5334-5336

Unprecedented thermal rearrangement of push–pull-chromophore[60]fullerene conjugates: formation of chiral 1,2,9,12-tetrakis-adducts

M. Yamada, W. B. Schweizer, F. Schoenebeck and F. Diederich, Chem. Commun., 2010, 46, 5334 DOI: 10.1039/C0CC00881H

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