Issue 35, 2010
From the journal:

Chemical Communications

Ordered mesoporous materials as solid supports for rhodium–diphosphinecatalysts with remarkable hydroformylation activity†

Fabrizio Marras,a   Jia Wang,b   Marc-Olivier Coppensbc  and  Joost N. H. Reek*a  

* Corresponding authors

a Supramolecular and Homogeneous Catalysis Group, van't Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands
E-mail: j.n.h.reek@uva.nl
Fax: +31 20 5255604
Tel: +31 20 5256459

b DelftChemTech, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands

c Department of Chemical and Biological Engineering, Rensselaer Polytechnic Institute, 110 8th Street, Troy, USA
E-mail: coppens@rpi.edu
Fax: +1 518 276 3089
Tel: +1 518 276 2671

Abstract

A rhodium–diphosphine complex based on Xantphos-type ligands was anchored on mesoporous silica SBA-15, and the material showed remarkably high catalytic activity in the hydroformylation of 1-octene, even exceeding its homogeneous analogue under certain conditions.

Graphical abstract: Ordered mesoporous materials as solid supports for rhodium–diphosphine catalysts with remarkable hydroformylation activity

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Article information

DOI
https://doi.org/10.1039/C0CC00924E
Article type
Communication
Submitted
14 Apr 2010
Accepted
19 Jul 2010
First published
09 Aug 2010

Chem. Commun., 2010,46, 6587-6589

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Ordered mesoporous materials as solid supports for rhodium–diphosphine catalysts with remarkable hydroformylation activity

F. Marras, J. Wang, M. Coppens and J. N. H. Reek, Chem. Commun., 2010, 46, 6587 DOI: 10.1039/C0CC00924E

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