Issue 33, 2010
From the journal:

Chemical Communications

Encapsulation and selective recognition of sulfate anion in an azamacrocycle in water†

John S. Mendy,a   Marcy L. Pilate,a   Toyketa Horne,a   Victor W. Dayb  and  Md. Alamgir Hossain*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Jackson State University, 1400 J. R. Lynch Street, P.O. Box 17910, Jackson, USA
E-mail: alamgir@chem.jsums.edu
Fax: +1 601-979-3674
Tel: +1 601-979-3748

b Department of Chemistry, University of Kansas, Lawrence, USA

Abstract

Structural characterization of a sulfate complex with an azamacrocycle suggests that one sulfate is encapsulated in the macrocyclic cavity with eight hydrogen bonds; a significant selectivity of the host was observed for sulfate over halides, nitrate and perchlorate as evaluated by 1H NMR studies in water.

Graphical abstract: Encapsulation and selective recognition of sulfate anion in an azamacrocycle in water

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Article information

DOI
https://doi.org/10.1039/C0CC01699C
Article type
Communication
Submitted
02 Jun 2010
Accepted
21 Jun 2010
First published
23 Jul 2010

Chem. Commun., 2010,46, 6084-6086

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Encapsulation and selective recognition of sulfate anion in an azamacrocycle in water

J. S. Mendy, M. L. Pilate, T. Horne, V. W. Day and Md. A. Hossain, Chem. Commun., 2010, 46, 6084 DOI: 10.1039/C0CC01699C

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