Issue 42, 2010

FeIII/FeII regular charge order in metal–organic framework

Abstract

The hydrolysis of the DMF solvent (DMF = N,N′-dimethylformamide) generates in situ the template cations DMA+ (dimethylammonium cation): it leads to the first MOF type solid FeIII0.5FeII0.5(OH,F)(O2C–C6H4–CO2)·0.5DMA with a regular charge order FeIII/FeII and an anionic framework with pores filled by counter-cations which behaves as a quasi-1D AF system with alternate localized FeII and FeIII moments.

Graphical abstract: FeIII/FeII regular charge order in metal–organic framework

Supplementary files

Article information

Article type
Communication
Submitted
28 Jun 2010
Accepted
07 Sep 2010
First published
23 Sep 2010

Chem. Commun., 2010,46, 7987-7989

FeIII/FeII regular charge order in metal–organic framework

M. E. Medina, Y. Dumont, J. Grenèche and F. Millange, Chem. Commun., 2010, 46, 7987 DOI: 10.1039/C0CC02161J

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