Issue 43, 2010

Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

Abstract

We show that a redox active {Fe4S4}2+cubane assembly covalently bound within a cysteinyl–alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.

Graphical abstract: Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

  • This article is part of the themed collection: Hydrogen

Supplementary files

Article information

Article type
Communication
Submitted
02 Aug 2010
Accepted
07 Sep 2010
First published
05 Oct 2010

Chem. Commun., 2010,46, 8189-8191

Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

S. Ibrahim, P. M. Woi, Y. Alias and C. J. Pickett, Chem. Commun., 2010, 46, 8189 DOI: 10.1039/C0CC02962A

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