Multilayered nanofibers from stacks of single-molecular thick nanosheets of hexakis(alkoxy)triphenylenes

Gayane Koshkakaryan; Peng Jiang; Virginia Altoe; Dennis Cao; Liana M. Klivansky; Yue Zhang; Sungwook Chung; Allard Katan; Florent Martin; Miquel Salmeron; Biwu Ma; Shaul Aloni; Yi Liu

doi:10.1039/C0CC03942J

Multilayered nanofibers from stacks of single-molecular thick nanosheets of hexakis(alkoxy)triphenylenes†

Gayane Koshkakaryan,^a Peng Jiang,^ab Virginia Altoe,^a Dennis Cao,^a Liana M. Klivansky,^a Yue Zhang,^a Sungwook Chung,^a Allard Katan,^ab Florent Martin,^ab Miquel Salmeron,^ab Biwu Ma,^a Shaul Aloni^a and Yi Liu*^a

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* Corresponding authors

^a The Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, California, USA
E-mail: yliu@lbl.gov
Fax: +1-510-486-7413
Tel: +1-510-486-6287

^b Materials Science and Engineering, University of California, Berkeley

Abstract

Symmetrically substituted hexakis(alkoxy)triphenylene (HAT) derivatives were assembled into single molecular thick 2D nanosheets, which stacked further to give multilayered nanofibers through a convenient solution process. Detailed information on molecular arrangement was unraveled by various imaging techniques and diffraction studies.

Chemical Communications

Multilayered nanofibers from stacks of single-molecular thick nanosheets of hexakis(alkoxy)triphenylenes†

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Multilayered nanofibers from stacks of single-molecular thick nanosheets of hexakis(alkoxy)triphenylenes

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