Issue 7, 2011
From the journal:

Chemical Communications

One pot production of 5-hydroxymethylfurfural with high yield from cellulose by a Brønsted–Lewis–surfactant-combined heteropolyacid catalyst†

Shun Zhao,a   Mingxing Cheng,a   Junzi Li,a   Juan Tiana  and  Xiaohong Wang*a  

* Corresponding authors

a Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, 5268 Renmin Street, Changchun 130024, Jilin Province, PR China
E-mail: wangxh665@nenu.edu.cn
Fax: +86 431-85099759

Abstract

A Brønsted–Lewis–surfactant-combined heteropolyacid (HPA) Cr[(DS)H2PW12O40]3 has been synthesized, and is used as a heterogeneous catalyst for the conversion of cellulose to 5-hydroxymethylfurfural in one pot within 2 h at 150 °C with 77.1% conversion and 52.7% yield. This micellar HPA catalyst shows stability and can be recycled by simple separation process.

Graphical abstract: One pot production of 5-hydroxymethylfurfural with high yield from cellulose by a Brønsted–Lewis–surfactant-combined heteropolyacid catalyst

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Article information

DOI
https://doi.org/10.1039/C0CC04444J
Article type
Communication
Submitted
16 Oct 2010
Accepted
06 Dec 2010
First published
04 Jan 2011

Chem. Commun., 2011,47, 2176-2178

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One pot production of 5-hydroxymethylfurfural with high yield from cellulose by a Brønsted–Lewis–surfactant-combined heteropolyacid catalyst

S. Zhao, M. Cheng, J. Li, J. Tian and X. Wang, Chem. Commun., 2011, 47, 2176 DOI: 10.1039/C0CC04444J

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