Issue 11, 2011

Compartmental Schiff-base ligands—a rich library of tectons in designing magnetic and luminescent materials

Abstract

The binuclear complexes (3d–3d, 3d–3d′, 3d–4f) with compartmental ligands can efficiently act as tectons in crystal engineering. Various high nuclearity clusters and coordination polymers can be easily obtained by choosing the appropriate spacers. The main interest in such systems arises from their magnetic and photophysical properties. Moreover, 3d–3d′ and 3d–4f complexes are useful precursors in designing heterotrimetallic systems with relevance in molecular magnetism.

Graphical abstract: Compartmental Schiff-base ligands—a rich library of tectons in designing magnetic and luminescent materials

Article information

Article type
Feature Article
Submitted
19 Oct 2010
Accepted
13 Dec 2010
First published
18 Jan 2011

Chem. Commun., 2011,47, 3025-3042

Compartmental Schiff-base ligands—a rich library of tectons in designing magnetic and luminescent materials

M. Andruh, Chem. Commun., 2011, 47, 3025 DOI: 10.1039/C0CC04506C

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