Issue 13, 2011

Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(ii) frameworks

Abstract

A unique 4-fold interpenetrated (10,3)-b copper(II) framework exhibits reversible dehydration and rehydration in a single-crystal-to-single-crystal (SC–SC) process, and the dehydrated material can encapsulate CH3OH molecules, again in a SC–SC fashion, and shows selective adsorption of H2 and CO2 over N2.

Graphical abstract: Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(ii) frameworks

Supplementary files

Article information

Article type
Communication
Submitted
29 Oct 2010
Accepted
17 Jan 2011
First published
02 Feb 2011

Chem. Commun., 2011,47, 3787-3789

Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(II) frameworks

M. Chen, M. Chen, S. Takamizawa, T. Okamura, J. Fan and W. Sun, Chem. Commun., 2011, 47, 3787 DOI: 10.1039/C0CC04689B

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