Issue 14, 2011
From the journal:

Chemical Communications

A simple topological identification method for highly (3,12)-connected 3D MOFs showing anion exchange and luminescent properties†

Qing-Yuan Yang,a   Kang Li,a   Jian Luo,a   Mei Pana  and  Cheng-Yong Su*ab  

* Corresponding authors

a KLGHEI of Environment and Energy Chemistry, MOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: cesscy@mail.sysu.edu.cn
Fax: +86 20-8411-5178

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Abstract

Reaction of a semi-rigid tripodal ligand 1,1′,1′′-(2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene)tripyridinium-4-olate) (TTP) with Ln3+ (Ln = Eu, Gd) afforded rare (3,12)-connected metal–organic frameworks (MOFs). A topological simplification of such highly connected 3D MOFs on the basis of 2D CdI2 (3,6)-nets is proposed. The luminescent and anion exchange properties of the compounds were determined.

Graphical abstract: A simple topological identification method for highly (3,12)-connected 3D MOFs showing anion exchange and luminescent properties

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Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CC05464J
Article type
Communication
Submitted
08 Dec 2010
Accepted
08 Feb 2011
First published
25 Feb 2011

Chem. Commun., 2011,47, 4234-4236

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A simple topological identification method for highly (3,12)-connected 3D MOFs showing anion exchange and luminescent properties

Q. Yang, K. Li, J. Luo, M. Pan and C. Su, Chem. Commun., 2011, 47, 4234 DOI: 10.1039/C0CC05464J

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