Issue 15, 2011

Thermochromic properties of low-melting ionic uranyl isothiocyanate complexes

Abstract

Temperature-dependent yellow-to-red colour changes of uranyl thiocyanate complexes with 1-alkyl-3-methylimidazolium cations have been studied by different spectroscopic methods and this phenomenon is attributed to changes in the local environment of the uranyl ion, including the coordination number, as well as to cation–anion interactions.

Graphical abstract: Thermochromic properties of low-melting ionic uranyl isothiocyanate complexes

Supplementary files

Article information

Article type
Communication
Submitted
13 Dec 2010
Accepted
23 Feb 2011
First published
11 Mar 2011

Chem. Commun., 2011,47, 4490-4492

Thermochromic properties of low-melting ionic uranyl isothiocyanate complexes

N. Aoyagi, K. Shimojo, N. R. Brooks, R. Nagaishi, H. Naganawa, K. V. Hecke, L. V. Meervelt, K. Binnemans and T. Kimura, Chem. Commun., 2011, 47, 4490 DOI: 10.1039/C0CC05550F

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