Stability and growth behavior of transition metal nanoparticles in ionic liquids prepared by thermal evaporation: how stable are they really?

Abstract

Recently we developed an access to metal- and metal-oxide colloids based on thermal evaporation of metals into ionic liquids (ILs). Here we present systematic studies on the long-time stability of gold and copper nanoparticles (NPs) in different ILs. The influence of metal concentration and temperature on the ripening of the as-prepared gold NPs in different ILs was investigated by transmission electron microscopy (TEM) and UV-vis absorption measurements. Short alkyl chain-length-methyl-imidazolium salts with weakly coordinating perfluorinated counter anions (PF₆, BF₄ or Tf₂N, bis(trifluoromethanesulfonyl)amide) were found to be better stabilizers compared to ILs with cations bearing long alkyl chains (trihexyltetradecylphosphonium, 1-octyl-3-methylimidazolium) and anions of higher coordination strength (DCA, dicyanamide). In the latter ILs fast particle growth and agglomeration was observed. In the well-stabilizing ILs initially very small NPs form which undergo a similar ripening process at room temperature as at higher temperatures. The final particle size depends largely on the used IL and the metal and to a minor extent on the temperature. The metal concentration seems to be an unimportant factor.