Studies in catalytic C–H amination involving nitrene C–H insertion

Florence Collet; Camille Lescot; Chungen Liang; Philippe Dauban

doi:10.1039/C0DT00283F

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Studies in catalytic C–H amination involving nitrene C–H insertion†‡

Florence Collet,^a Camille Lescot,^a Chungen Liang^a and Philippe Dauban*^a

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* Corresponding authors

^a Institut de Chimie des Substances Naturelles, UPR 2301 CNRS, Centre de Recherches de Gif, Avenue de la Terrasse, Gif-sur-Yvette Cedex, France
E-mail: philippe.dauban@icsn.cnrs-gif.fr
Fax: +33 1 6907 7247
Tel: +33 1 6982 4560

Abstract

Stereoselective catalytic intermolecular C–H amination of complex molecules is reported. Site-selective functionalizations occur with very good yields up to 91% and excellent d.e.s up to 99%. However, the precise nature of the nitrene C–H insertion remains a matter of debate despite several physical organic experiments.

This article is part of the themed collection: Dalton Discussion 12: Catalytic C–H and C–X bond activation (DD12)

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Article information

DOI: https://doi.org/10.1039/C0DT00283F
Article type: Paper
Submitted: 09 Apr 2010
Accepted: 21 Jun 2010
First published: 08 Oct 2010

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Dalton Trans., 2010,39, 10401-10413

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Studies in catalytic C–H amination involving nitrene C–H insertion

F. Collet, C. Lescot, C. Liang and P. Dauban, Dalton Trans., 2010, 39, 10401 DOI: 10.1039/C0DT00283F

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Dalton Transactions

Studies in catalytic C–H amination involving nitrene C–H insertion†‡

Abstract

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Studies in catalytic C–H amination involving nitrene C–H insertion

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