Issue 6, 2011
From the journal:

Dalton Transactions

Platinum(iv) centres with agostic interactions from either sp2 or sp3 C–H bonds†

Sarah H. Crosby,a   Robert J. Deeth,a   Guy J. Clarksona  and  Jonathan P. Rourke*a  

* Corresponding authors

a Department of Chemistry, University of Warwick, Coventry, UK
E-mail: j.rourke@warwick.ac.uk
Fax: 44 2476 524112
Tel: 44 2476 523263

Abstract

Agostic complexes of platinum(IV) have been isolated and characterised. A Pt(II) sp3 agostic complex maintains the agostic interaction upon oxidation giving a Pt(IV) sp3 agostic complex; in another Pt(IV) complex the agostic interaction from an sp2 C–H bond is sufficient to displace another ligand.

Graphical abstract: Platinum(iv) centres with agostic interactions from either sp2 or sp3 C–H bonds

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Article information

DOI
https://doi.org/10.1039/C0DT01428A
Article type
Communication
Submitted
20 Oct 2010
Accepted
02 Dec 2010
First published
04 Jan 2011

Dalton Trans., 2011,40, 1227-1229

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Platinum(IV) centres with agostic interactions from either sp2 or sp3 C–H bonds

S. H. Crosby, R. J. Deeth, G. J. Clarkson and J. P. Rourke, Dalton Trans., 2011, 40, 1227 DOI: 10.1039/C0DT01428A

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