Issue 26, 2011

Novel magnetic functionalities of Prussian blue analogs

Abstract

Cyano-bridged bimetal assemblies demonstrate novel magnetic functionalities, particularly Prussian blue analogs, which have unique properties. In this perspective, we describe a charge-transfer phase transition, reversible photomagnetism, second harmonic generation and magnetization-induced second harmonic generation, ferroelectric ferromagnetism, humidity-sensitive magnetism, high ionic conductivity, and a coupling effect (which we named spin-ionics) between ionic conduction and magnetic ordering with Prussian blue analogs.

Graphical abstract: Novel magnetic functionalities of Prussian blue analogs

Article information

Article type
Perspective
Submitted
25 Dec 2010
Accepted
28 Feb 2011
First published
29 Mar 2011

Dalton Trans., 2011,40, 6825-6833

Novel magnetic functionalities of Prussian blue analogs

H. Tokoro and S. Ohkoshi, Dalton Trans., 2011, 40, 6825 DOI: 10.1039/C0DT01829E

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