Issue 3, 2011

Pentaalkylmethylguanidinium methylcarbonates – versatile precursors for the preparation of halide-free and metal-free guanidinium-based ILs

Abstract

Pentaalkylmethylguanidinium methylcarbonates 6 can easily be prepared from pentaalkylguanidines 5 and dimethyl carbonate (DMC) in a sustainable solvent-free synthesis. Most of the title compounds are room temperature ionic liquids (RTILs) which provide convenient access to halide-free guanidinium-based ILs (GILs) 7via acid–base reactions and subsequent decarboxylation, similar to industrially important imidazolium methylcarbonates 1.

Graphical abstract: Pentaalkylmethylguanidinium methylcarbonates – versatile precursors for the preparation of halide-free and metal-free guanidinium-based ILs

Supplementary files

Article information

Article type
Paper
Submitted
15 Oct 2010
Accepted
07 Dec 2010
First published
18 Jan 2011

Green Chem., 2011,13, 608-618

Pentaalkylmethylguanidinium methylcarbonates – versatile precursors for the preparation of halide-free and metal-free guanidinium-based ILs

B. Oelkers and J. Sundermeyer, Green Chem., 2011, 13, 608 DOI: 10.1039/C0GC00698J

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