Selective photocatalytic reductions of nitrobenzene derivatives using PbBiO2X and blue light

Stefan Füldner; Patrick Pohla; Hanna Bartling; Stephan Dankesreiter; Roland Stadler; Michael Gruber; Arno Pfitzner; Burkhard König

doi:10.1039/C0GC00857E

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Selective photocatalytic reductions of nitrobenzene derivatives using PbBiO₂X and blue light†

Stefan Füldner,^a Patrick Pohla,^b Hanna Bartling,^a Stephan Dankesreiter,^b Roland Stadler,^b Michael Gruber,^c Arno Pfitzner*^b and Burkhard König*^a

Author affiliations

* Corresponding authors

^a Institute of Organic Chemistry, University of Regensburg, Universitätsstrasse 31, Regensburg, Germany
E-mail: Burkhard.koenig@chemie.uni-regensburg.de
Fax: +49 941 9434566
Tel: +49 941 9434575

^b Institute of Inorganic Chemistry, University of Regensburg, Universitätsstrasse 31, Germany
E-mail: arno.pfitzner@chemie.uni-regensburg.de
Fax: +49 941 943 4983
Tel: +49 941 943 4552

^c Department of Anaesthesia, University Hospital Regensburg, Regensburg, Germany
E-mail: michael.gruber@klinik.uni-regensburg.de
Fax: +49 941 944 7801
Tel: +49 941 944 7870

Abstract

Blue light irradiation of heterogeneous photocatalysts PbBiO₂X (X = Cl, Br) in the presence of triethanolamine as an electron donor leads to hydrogen evolution, and the selective, clean and complete reduction of nitrobenzene derivatives to their corresponding anilines.

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Article information

DOI: https://doi.org/10.1039/C0GC00857E
Article type: Paper
Submitted: 28 Nov 2010
Accepted: 05 Jan 2011
First published: 09 Feb 2011

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Green Chem., 2011,13, 640-643

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Selective photocatalytic reductions of nitrobenzene derivatives using PbBiO₂X and blue light

S. Füldner, P. Pohla, H. Bartling, S. Dankesreiter, R. Stadler, M. Gruber, A. Pfitzner and B. König, Green Chem., 2011, 13, 640 DOI: 10.1039/C0GC00857E

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