Issue 5, 2011
From the journal:

Green Chemistry

Highly chemoselective metal-free oxidation of sulfides with diluted H2O2 in a continuous flow reactor

Raimondo Maggi,*a   Soheila Chitsaz,b   Stefan Loebbecke,b   Calogero G. Piscopo,ab   Giovanni Sartoria  and  Maud Schwarzerb  

* Corresponding authors

a “Clean Synthetic Methodology Group”, Dipartimento di Chimica Organica e Industriale dell'Università, Parco Area delle Scienze 17A, Parma, Italy
E-mail: raimondo.maggi@unipr.it
Fax: +39 0521 905472
Tel: +39 0521 905411

b Fraunhofer Institute for Chemical Technology ICT, Joseph von Fraunhofer Str. 7, Pfinztal, Germany

Abstract

The oxidation of different aromatic sulfides catalyzed by Amberlite IR 120 H was performed with a very high efficiency in a continuous flow reactor. For the first time this reaction takes place under mild conditions using only 3% aqueous hydrogen peroxide and no metal catalyst.

Graphical abstract: Highly chemoselective metal-free oxidation of sulfides with diluted H2O2 in a continuous flow reactor

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Article information

DOI
https://doi.org/10.1039/C0GC00887G
Article type
Communication
Submitted
06 Dec 2010
Accepted
02 Mar 2011
First published
18 Mar 2011

Green Chem., 2011,13, 1121-1123

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Highly chemoselective metal-free oxidation of sulfides with diluted H2O2 in a continuous flow reactor

R. Maggi, S. Chitsaz, S. Loebbecke, C. G. Piscopo, G. Sartori and M. Schwarzer, Green Chem., 2011, 13, 1121 DOI: 10.1039/C0GC00887G

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