Issue 7, 2011
From the journal:

Journal of Materials Chemistry

Nanoporous copolymer networks through multiple Friedel–Crafts-alkylation—studies on hydrogen and methane storage†

Matthias Georg Schwab,*a   Angela Lennert,bd   Jörg Pahnke,b   Gerhard Jonschker,b   Matthias Koch,b   Irena Senkovska,c   Matthias Rehahnd  and  Stefan Kaskel*c  

* Corresponding authors

a Max Planck Institute for Polymer Research, Ackermannweg 10, Mainz, Germany
E-mail: schwab@mpip-mainz.mpg.de
Fax: +49 6131-379100
Tel: +49 6131-379285

b Merck KGaA, Frankfurter Straße 250, Darmstadt, Germany

c Department of Inorganic Chemistry, Dresden University of Technology, Bergstaße 66, Dresden, Germany
E-mail: stefan.kaskel@chemie.tu-dresden.de
Fax: +49 351-46337287
Tel: +49 351-46334885

d Ernst-Berl-Institute for Technical and Macromolecular Chemistry, Darmstadt University of Technology, Petersenstrasse 22, Darmstadt, Germany

Abstract

A novel series of hypercrosslinked copolymer networks was obtained by the statistical co-condensation of 4,4′-bis(chloromethyl)biphenyl with a series of non-functionalized fluorene-based monomers under Friedel–Crafts catalysis. The resulting nanoporous polymer materials exhibit high BET surface areas of up to 1800 m2 g−1 as derived from nitrogen physisorption. The hydrogen and methane uptakes were examined with respect to the chemical composition of these novel polymer adsorbents.

Graphical abstract: Nanoporous copolymer networks through multiple Friedel–Crafts-alkylation—studies on hydrogen and methane storage

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Article information

DOI
https://doi.org/10.1039/C0JM03017A
Article type
Paper
Submitted
09 Sep 2010
Accepted
24 Nov 2010
First published
23 Dec 2010

J. Mater. Chem., 2011,21, 2131-2135

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Nanoporous copolymer networks through multiple Friedel–Crafts-alkylation—studies on hydrogen and methane storage

M. G. Schwab, A. Lennert, J. Pahnke, G. Jonschker, M. Koch, I. Senkovska, M. Rehahn and S. Kaskel, J. Mater. Chem., 2011, 21, 2131 DOI: 10.1039/C0JM03017A

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