Issue 11, 2010
From the journal:

New Journal of Chemistry

Synthesis, crystal structures, luminescent and thermal properties of two new metal–organic coordination polymers based on zinc(ii) carboxylates†‡

Sergey A. Sapchenko,ab   Danil N. Dybtsev,ac   Denis G. Samsonenkoab  and  Vladimir P. Fedin*ab  

* Corresponding authors

a Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Akad. Lavrentiev Av., Russian Federation
E-mail: cluster@niic.nsc.ru
Fax: +7 (383) 330 9489
Tel: +7 (383) 330 9490

b Novosibirsk State University, 2 Pirogova Street, Russian Federation

c Division of the Advanced Materials Science, POSTECH, San 31, Hyojadong, Republic of Korea

Abstract

Two new metal–organic coordination polymers, [NH2(CH3)2]2[Zn3(bdc)4]·DMF·H2O (1) (H2bdc = 1,4-benzenedicarboxylic acid) and [NH2(CH3)2]2[Zn3(bpdc)4]·5DMF (2) (H2bpdc = 4,4′-biphenyldicarboxylic acid), were synthesized by heating a DMF solution of Zn(NO3)2·6H2O, [NH2(CH3)2]Cl and organic carboxylic acids. Single-crystal X-ray structure analysis reveals that these compounds have 3D anionic framework structures built from zinc(II) carboxylate layers linked by carboxylate anions. Compounds 1 and 2 were characterized by IR, TGA and XRPD, and their luminescent properties were also investigated.

Graphical abstract: Synthesis, crystal structures, luminescent and thermal properties of two new metal–organic coordination polymers based on zinc(ii) carboxylates

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Article information

DOI
https://doi.org/10.1039/C0NJ00196A
Article type
Paper
Submitted
15 Mar 2010
Accepted
10 Jun 2010
First published
07 Jul 2010

New J. Chem., 2010,34, 2445-2450

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Synthesis, crystal structures, luminescent and thermal properties of two new metal–organic coordination polymers based on zinc(II) carboxylates

S. A. Sapchenko, D. N. Dybtsev, D. G. Samsonenko and V. P. Fedin, New J. Chem., 2010, 34, 2445 DOI: 10.1039/C0NJ00196A

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