Issue 7, 2010
From the journal:

Polymer Chemistry

Highly efficient, stoichiometric radical exchange reactions using isoindoline profluorescent nitroxides†

James P. Blinco,‡*ab   Kathryn E. Fairfull-Smith,b   Aaron S. Micallefa  and  Steven E. Bottle*b  

* Corresponding authors

a Centre for Magnetic Resonance and Australian Institute for Bioengineering and Nanotechnology, University of Queensland, Brisbane, Queensland, Australia
Fax: +61 (0)7 3346 3973
Tel: +61 (0)7 3346 3864

b ARC Centre of Excellence for Free Radical Chemistry and Biotechnology, Queensland University of Technology, Brisbane, Queensland, Australia
E-mail: s.bottle@qut.edu.au
Fax: +61 (0)7 3138 1804
Tel: +61 (0)7 3138 1356

Abstract

Exchange reactions between the isoindoline profluorescent nitroxide 1,1,3,3-tetramethyldibenzo[e,g]isoindolin-2-yloxyl (TMDBIO) and a TEMPO capped polystyrene were carried out. High conversions to the desired products were achieved using only stoichiometric ratios of nitroxide relative to polymer. The scope of this study was expanded by exploiting a di-nitroxide 9,10-bis(5-[1,1,3,3-tetramethylisoindolin-2-yloxy])anthracene (BTMIOA) as a connector between two polymer chains forming PS–nitroxide–PS systems.

Graphical abstract: Highly efficient, stoichiometric radical exchange reactions using isoindoline profluorescent nitroxides

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Article information

DOI
https://doi.org/10.1039/C0PY00015A
Article type
Paper
Submitted
12 Jan 2010
Accepted
26 Mar 2010
First published
08 May 2010

Polym. Chem., 2010,1, 1009-1012

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Highly efficient, stoichiometric radical exchange reactions using isoindoline profluorescent nitroxides

J. P. Blinco, K. E. Fairfull-Smith, A. S. Micallef and S. E. Bottle*, Polym. Chem., 2010, 1, 1009 DOI: 10.1039/C0PY00015A

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