Issue 6, 2010

Highly enantio-, regio- and diastereo-selective one-pot [2 + 3]-cycloaddition reaction viaisomerization of 3-butynoates to allenoates,

Abstract

Phosphine-catalyzed one-pot isomerization and [2 + 3]-cycloaddition of 3-butynoates with electron-deficient olefins affords highly functionalized cyclopentenes with both good yields and excellent selectivities of up to 99%.

Graphical abstract: Highly enantio-, regio- and diastereo-selective one-pot [2 + 3]-cycloaddition reaction via isomerization of 3-butynoates to allenoates,

Supplementary files

Article information

Article type
Edge Article
Submitted
27 Jan 2010
Accepted
05 Aug 2010
First published
06 Sep 2010

Chem. Sci., 2010,1, 739-742

Highly enantio-, regio- and diastereo-selective one-pot [2 + 3]-cycloaddition reaction via isomerization of 3-butynoates to allenoates,

M. Sampath and T. Loh, Chem. Sci., 2010, 1, 739 DOI: 10.1039/C0SC00123F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements