Issue 3, 2011

Stable singlet carbenes as mimics for transition metal centers

Abstract

This perspective summarizes recent results, which demonstrate that stable carbenes can activate small molecules (CO, H2, NH3 and P4) and stabilize highly reactive intermediates (main group elements in the zero oxidation state and paramagnetic species). These two tasks were previously exclusive for transition metal complexes.

Graphical abstract: Stable singlet carbenes as mimics for transition metal centers

Article information

Article type
Perspective
Submitted
23 Jul 2010
Accepted
09 Aug 2010
First published
15 Sep 2010

Chem. Sci., 2011,2, 389-399

Stable singlet carbenes as mimics for transition metal centers

D. Martin, M. Soleilhavoup and G. Bertrand, Chem. Sci., 2011, 2, 389 DOI: 10.1039/C0SC00388C

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